1981

JEE Main 1981 Chemistry question on Some Basic Concepts of Chemistry

If 0.50 mole of BaCl2\text{BaCl}_2 is mixed with 0.20 mole of Na3PO4\text{Na}_3\text{PO}_4, the maximum number of moles of Ba3(PO4)2\text{Ba}_3(\text{PO}_4)_2 that can be formed is
  1. A.
    0.70
  2. B.
    0.50
  3. C.
    0.20
  4. D.
    0.10
Show answer and solution

Correct option: D

Solution

The balanced reaction is: 3 BaCl₂ + 2 Na₃PO₄ → Ba₃(PO₄)₂ + 6 NaCl.

Check both reactants as potential limiting reagents:
- From 0.50 mol BaCl₂: moles of Ba₃(PO₄)₂ = 0.50 × (1/3) = 0.167 mol
- From 0.20 mol Na₃PO₄: moles of Ba₃(PO₄)₂ = 0.20 × (1/2) = 0.10 mol

Na₃PO₄ gives the smaller amount, so it is the limiting reagent, and the maximum moles of Ba₃(PO₄)₂ formed is 0.10.

[1981]

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