NEET 2022

NEET 2022 Chemistry question on Redox and Electrochemistry

At 298 K, the standard electrode potentials of Cu2+/Cu\text{Cu}^{2+}/\text{Cu}, Zn2+/Zn\text{Zn}^{2+}/\text{Zn}, Fe2+/Fe\text{Fe}^{2+}/\text{Fe} and Ag+/Ag\text{Ag}^+/\text{Ag} are 0.34 V, –0.76 V, –0.44 V and 0.80 V, respectively.
On the basis of standard electrode potential, predict which of the following reaction cannot occur?
  1. A.
    CuSO4(aq)+Zn(s)→ZnSO4(aq)+Cu(s)\text{CuSO}_4(aq) + \text{Zn}(s) \rightarrow \text{ZnSO}_4(aq) + \text{Cu}(s)
  2. B.
    CuSO4(aq)+Fe(s)→FeSO4(aq)+Cu(s)\text{CuSO}_4(aq) + \text{Fe}(s) \rightarrow \text{FeSO}_4(aq) + \text{Cu}(s)
  3. C.
    FeSO4(aq)+Zn(s)→ZnSO4(aq)+Fe(s)\text{FeSO}_4(aq) + \text{Zn}(s) \rightarrow \text{ZnSO}_4(aq) + \text{Fe}(s)
  4. D.
    2CuSO4(aq)+2Ag(s)→2Cu(s)+Ag2SO4(aq)2\text{CuSO}_4(aq) + 2\text{Ag}(s) \rightarrow 2\text{Cu}(s) + \text{Ag}_2\text{SO}_4(aq)
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Correct option: D

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