JEE Main 2023 · 29 Jan · Shift 1

JEE Main 2023 Chemistry question on Biomolecules

Number of cyclic tripeptides formed with 2 amino acids A and B is:
  1. A.
    2
  2. B.
    4
  3. C.
    5
  4. D.
    3
Show answer and solution

Correct option: A

Solution

A cyclic tripeptide with 2 amino acids A and B must use all 3 positions, so the possible compositions are AAB (2 A's, 1 B) or ABB (1 A, 2 B's).

For a cyclic tripeptide, rotations of the same sequence are identical. For AAB: the distinct cyclic arrangement is only one — A-A-B (since rotating A-A-B gives A-B-A and B-A-A, but these are all the same cyclic sequence). Similarly for ABB, there is only one distinct cyclic arrangement.

So total = 1 (from AAB) + 1 (from ABB) = 2 distinct cyclic tripeptides.

[JEE Main 2023 · 29 Jan · Shift 1]

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