JEE Main 2023 · 25 Jan · Shift 2

JEE Main 2023 Chemistry question on Hydrogen and s-Block Elements

Match List I with List II

LIST ILIST II
A. Cobalt catalystI. (H2+Cl2)(H_2 + Cl_2) production
B. SyngasII. Water gas production
C. Nickel catalystIII. Coal gasification
D. Brine solutionIV. Methanol production


Choose the correct answer from the options given below:
  1. A.
    A-IV, B-III, C-II, D-I
  2. B.
    A-II, B-III, C-IV, D-I
  3. C.
    A-IV, B-III, C-I, D-II
  4. D.
    A-IV, B-I, C-II, D-III
Show answer and solution

Correct option: A

Solution

Cobalt catalyst is used in Fischer-Tropsch synthesis and also in methanol production (IV). Syngas (CO + H₂) is produced by coal gasification (III), where coal reacts with steam/oxygen at high temperatures. Nickel catalyst is used in the steam reforming of hydrocarbons to produce water gas/syngas, but specifically here Nickel catalyst → water gas production (II), as Ni is the catalyst in the steam-methane reforming that generates H₂ + CO (water gas). Electrolysis of brine solution (NaCl dissolved in water) produces H₂ at cathode and Cl₂ at anode, i.e., (H₂ + Cl₂) production (I). This gives A-IV, B-III, C-II, D-I.

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