JEE Advanced 2024 · Paper 1 · one or more correct

JEE Advanced 2024 Chemistry question on Alcohols Phenols and Ethers

Reaction of isoiso-propylbenzene with O2\mathrm{O_2} followed by the treatment with H3O+\mathrm{H_3O^+} forms phenol and a by-product P\mathbf{P}. Reaction of P\mathbf{P} with 3 equivalents of Cl2\mathrm{Cl_2} gives compound Q\mathbf{Q}. Treatment of Q\mathbf{Q} with Ca(OH)2\mathrm{Ca(OH)_2} produces compound R\mathbf{R} and calcium salt S\mathbf{S}. The correct statement(s) regarding P\mathbf{P}, Q\mathbf{Q}, R\mathbf{R} and S\mathbf{S} is(are)
  1. A.
    Reaction of P\mathbf{P} with R\mathbf{R} in the presence of KOH followed by acidification gives (HO)(CCl3)C(CH3)2\mathrm{(HO)(CCl_3)C(CH_3)_2} [structure shown: a carbon bearing HO and CCl3 attached to a C(CH3)2 group]
  2. B.
    Reaction of R\mathbf{R} with O2\mathrm{O_2} in the presence of light gives phosgene gas
  3. C.
    Q\mathbf{Q} reacts with aqueous NaOH to produce Cl3CCH2OH\mathrm{Cl_3CCH_2OH} and Cl3CCOONa\mathrm{Cl_3CCOONa}
  4. D.
    S\mathbf{S} on heating gives P\mathbf{P}
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Correct options: A, B, D

[JEE Advanced 2024 · Paper 1]

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