JEE Advanced 2023 · Paper 1

JEE Advanced 2023 Chemistry question on Coordination Compounds

Match the electronic configurations in List-I with appropriate metal complex ions in List-II and choose the correct option.
[Atomic Number: Fe = 26, Mn = 25, Co = 27]
List-I
(P) t2g6eg0t_{2g}^{6} e_g^{0}
(Q) t2g3eg2t_{2g}^{3} e_g^{2}
(R) e2t23e^{2} t_2^{3}
(S) t2g4eg2t_{2g}^{4} e_g^{2}
List-II
(1) [Fe(H2O)6]2+[\text{Fe}(\text{H}_2\text{O})_6]^{2+}
(2) [Mn(H2O)6]2+[\text{Mn}(\text{H}_2\text{O})_6]^{2+}
(3) [Co(NH3)6]3+[\text{Co}(\text{NH}_3)_6]^{3+}
(4) [FeCl4]−[\text{FeCl}_4]^{-}
(5) [CoCl4]2−[\text{CoCl}_4]^{2-}
  1. A.
    P→1;Q→4;R→2;S→3\text{P} \rightarrow 1; \text{Q} \rightarrow 4; \text{R} \rightarrow 2; \text{S} \rightarrow 3
  2. B.
    P→1;Q→2;R→4;S→5\text{P} \rightarrow 1; \text{Q} \rightarrow 2; \text{R} \rightarrow 4; \text{S} \rightarrow 5
  3. C.
    P→3;Q→2;R→5;S→1\text{P} \rightarrow 3; \text{Q} \rightarrow 2; \text{R} \rightarrow 5; \text{S} \rightarrow 1
  4. D.
    P→3;Q→2;R→4;S→1\text{P} \rightarrow 3; \text{Q} \rightarrow 2; \text{R} \rightarrow 4; \text{S} \rightarrow 1
Show answer

Correct option: D

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